The absence of a distinct theoretical description of XPS fitting has led to the publication of erroneous conclusions about surface chemistry. Despite computational advances and higher accessibility of software resources, it has been challenging to develop a chemically and physically meaningful approach to curve fitting. Curve fitting has been widely used for more than 50 years for extracting chemical information from the overlapping features in high-resolution XPS spectra. Over the past 30 years, x-ray photoelectron spectroscopy (XPS) has become the most widely used surface analysis tool and has been an essential component of many research studies.
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